文献类型：期刊文献

英文题名：Porous multishelled NiO hollow microspheres encapsulated within three-dimensional graphene as flexible free-standing electrodes for high-performance supercapacitors

作者：Zhang, Zhifang[1];Su, Xiaorui[1];Zhu, Yanyan[1];Chen, Zhonghui[2,3];Fang, Zebo[4];Luo, Xiaojing[1]

机构：[1]Shanghai Univ Elect Power, Coll Math & Phys, 2103 Pingliang Rd, Shanghai 200090, Peoples R China;[2]Henan Univ, Key Lab Special Funct Mat, Minist Educ, Sch Mat Sci & Engn, Kaifeng 475004, Peoples R China;[3]Henan Univ, Collaborat Innovat Ctr Nano Funct Mat & Applicat, Kaifeng 475004, Peoples R China;[4]Shaoxing Univ, Dept Phys, Shaoxing 312000, Peoples R China

年份：2019

卷号：11

期号：34

起止页码：16071

外文期刊名：NANOSCALE

收录：SCI-EXPANDED(收录号：WOS:000483691300031)、、EI(收录号：20193607408088)、Scopus(收录号：2-s2.0-85071715732)、WOS

基金：This work was supported by the National Natural Science Foundation of China (Grant No. 51672172, 51872186, and 11504227).

语种：英文

外文关键词：Aerogels - Amines - Capacitance - Data storage equipment - Electrolytes - Energy storage - Graphene - Microspheres - Nickel oxide - Supercapacitor

外文摘要：Exploration of electrode materials with well-defined nanostructures and good flexibility is an efficient approach for achieving high-performance and flexible energy storage systems. However, it is still challenging to well integrate active materials into flexible electrodes and simultaneously maintain satisfactory electrochemical performance. Herein, we successfully synthesize novel three-dimensional graphene (3DG)-encapsulated porous multishelled NiO hollow microsphere (3DG/pMS-NiO) composite aerogels via a modified self-templating method and a dopamine (DA)-assisted self-assembly route. The well-designed highly interconnected porous 3DG network and the close contact NiO-graphene structure of the 3DG/pMS-NiO composite aerogels offer multiple advantages such as high porosity and accessible area, improved conductivity, enhanced electrolyte diffusion and a simple electrode preparation process. Thus, the as-prepared flexible 3DG/pMS-NiO electrodes showed significantly improved specific capacitance of 710.4 F g(-1) at 0.5 A g(-1) and excellent rate capability with an ultrahigh capacitance retention of 92.5% at 10 A g(-1). In addition, the fabricated asymmetric supercapacitors (3DG/pMS-NiO//AC) showed a high specific capacitance of 34.4 F g(-1) at 1 A g(-1) with a voltage window of 0-1.6 V, a large energy density of 12.3 W h kg(-1) at a power density of 815.3 W kg(-1), and a decent cycling stability. This work profoundly enlightens the material design and electrode preparation, and even opens up an avenue for the development of high-performance and flexible energy storage systems.