文献类型：期刊文献

英文题名：Visible-Light-Induced alpha-Amino C-H Bond Arylation Enabled by Electron Donor-Acceptor Complexes

作者：Xu, Chang[1];Shen, Fang-Qi[1];Feng, Gaofeng[1];Jin, Jian[2]

机构：[1]Shaoxing Univ, Zhejiang Key Lab Alternat Technol Fine Chem Proc, Shaoxing 312000, Peoples R China;[2]Shanghai Inst Organ Chem, Ctr Excellence Mol Synth, CAS Key Lab Synthet Chem Nat Subst, Shanghai 200032, Peoples R China

年份：2021

卷号：23

期号：10

起止页码：3913

外文期刊名：ORGANIC LETTERS

收录：SCI-EXPANDED(收录号：WOS:000656057300022)、、Scopus(收录号：2-s2.0-85106468626)、WOS、CCR-EXPANDED(收录号：WOS:000656057300022)

基金：We are grateful for the financial support by National Natural Science Foundation of China (Grant Nos. 21676166 and 21302130) and Natural Science Foundation of Shanghai (19ZR1468700).

语种：英文

外文摘要：Enabled by electron donor-acceptor complexes, a novel visible-light-induced alpha-amino C-H bond arylation protocol, without a photoredox catalyst, has been disclosed. The protocol does not require any transition metal, oxidant, or exclusion of oxygen or moisture. A direct irradiation of the mixture of tertiary amines and benzonitriles with visible light in N,N-diethylethanamide in the presence of Cs2CO3 afforded a-arylated amines in good to excellent yields.