文献类型：期刊文献

英文题名：A σ,π-type monocarborane copper acetylide for regioselective 1,4-disubstituted 1,2,3-triazoles

作者：Zhang, Kang[1];Feng, Luting[1];Jin, Yujie[2];Liu, Jiyong[2];Duttwyler, Simon[2]

机构：[1]Shaoxing Univ, Yuanpei Coll, Qunxian Rd 2799, Shaoxing 312000, Peoples R China;[2]Zhejiang Univ, Dept Chem, Yuhangtang Rd 866, Hangzhou 310058, Peoples R China

年份：2025

外文期刊名：CHEMICAL COMMUNICATIONS

收录：SCI-EXPANDED(收录号：WOS:001420679700001)、、EI(收录号：20250717890070)、Scopus(收录号：2-s2.0-85217808538)、WOS

基金：This work was supported by the Natural Science Foundation of China (grant no. 22250610196) and the Funds for Basic Scientific Research of Shaoxing University (No. 2024LG015). We extend our special thanks to Pro. Dr Bernhard Spingler and Dr Xiaoli Yang for their valuable discussion

语种：英文

外文关键词：Copper compounds

外文摘要：A sigma,pi-bis(copper) acetylide complex, (CB11H11-12-C 00000000000000000 00000000000000000 00000000000000000 01111111111111110 00000000000000000 01111111111111110 00000000000000000 01111111111111110 00000000000000000 00000000000000000 00000000000000000 C)Cu2(PiPr3)3 (2), enables the formation of regioselective 1,4-disubstituted 1,2,3-triazoles containing monocarborane anion [CB11H12]-via CuAAC with organic azides under mild conditions. This method achieves 1,2,3-triazolylated monocarboranes (3) in up to 97% yield, including a luminescent compound with optoelectronic potential.