文献类型：期刊文献

中文题名：软模板法合成具有优异染料吸附性能的超微孔炭材料

英文题名：Soft Template Route for Synthesis of Super-microporous Carbons with Excellent Adsorption Property for Organic Dye

作者：刘华[1];王聪[1];邹旭[2];刘福建[1]

机构：[1]绍兴文理学院化学化工学院应用化学研究所;[2]太原师范学院化学系

年份：2013

卷号：51

期号：6

起止页码：1173

中文期刊名：吉林大学学报：理学版

收录：CSTPCD、、北大核心2011、北大核心、CSCD、CSCD2013_2014

基金：国家自然科学基金(批准号:21203122);高等学校博士后基金(批准号:2012M520062);绍兴市科技局公益项目(批准号:2012B70018)

语种：中文

中文关键词：超微孔材料;水热合成;炭材料;吸附;自组装

外文关键词：supermicroporous materials; hydrothermal synthesis; carbon based material; adsorption;self-assembly

中文摘要：以小分子炭氟表面活性剂[FSOCF3CF2CF2CF2CF2-(CH2CH2O)10](FSO)为超微孔模板剂,通过酚醛预聚物和FSO间的氢键自组装作用实现其分子间的自组装,经过水热处理和高温炭化合成超微孔炭材料,并对其进行X射线衍射(XRD)测试、氮气吸附测试和液相吸附性能测试.结果表明:该超微孔炭材料的孔结构有一定的规则性;比表面积为600m2/g,且孔径分布在超微孔范围(1.2nm);对有机染料(罗丹明B)的最大吸附容量为120mg/g.

外文摘要：Supermicroporous carbon with stable network has been successfully synthesized by the self assembly of carbon-fluorine surfactant [FSOCF3CF2CF2CF2CF2-（CH2CH2O）10] （FSO） with resol under high temperature hydrothermal conditions.After the carbonization of the sample at a high tempreture,which results in the shrinkage of the network,the small mesopore size carbon in the range of supermicroporous was obtained.XRD patterns show that the sample exhibits a certain order.N2 isotherm shows that the sample has a large BET surface area （600 m^2/g） and obviously supermieropore （1.2 nm）.Adsorption test shows that the resulted sample shows much better adsorption properties and a good recyclability,and the maximal adsorption capacity of organic dye RhB is 120 mg/g.