文献类型：期刊文献

英文题名：Palladium-catalyzed direct and regioselective C-H acyloxylation of indolizines

作者：Sun, Jinwei[1,2];Wang, Fuyao[1,2];Shen, Yongmiao[3];Zhi, Huizhen[4];Wu, Hui[1,2];Liu, Yun[1,2]

机构：[1]Jiangsu Normal Univ, Jiangsu Key Lab Green Synthet Chem Funct Mat, Xuzhou 221116, Jiangsu, Peoples R China;[2]Jiangsu Normal Univ, Inst Chem & Chem Engn, Xuzhou 221116, Jiangsu, Peoples R China;[3]Shaoxing Univ, Sch Chem & Chem Engn, Shaoxing 312000, Zhejiang, Peoples R China;[4]Nanjing Normal Univ, Sch Chem & Mat Sci, Nanjing 210046, Jiangsu, Peoples R China

年份：2015

卷号：13

期号：40

起止页码：10236

外文期刊名：ORGANIC & BIOMOLECULAR CHEMISTRY

收录：SCI-EXPANDED(收录号：WOS:000362729600019)、、EI(收录号：20154201385689)、Scopus(收录号：2-s2.0-84983119454)、WOS、CCR-EXPANDED(收录号：WOS:000362729600019)

基金：This work was supported by the National Natural Science Foundation of China (NSFC 21172188, 21202101), and the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

语种：英文

外文关键词：Activation analysis - Catalysis - Palladium

外文摘要：A direct and regioselective C1-acyloxylation of indolizines was developed via palladium-catalyzed C-H functionalization. A series of indolizines were successfully acyloxylated at the C1 position with the tolerance of a broad range of functional groups. In this reaction, high regioselectivity was achieved in the absence of a directing group. This work represents the first example of indolizine acyloxylation via C-H activation.