文献类型：期刊文献

英文题名：Polyacrylonitrile fiber mat-supported palladium catalyst for Mizoroki-Heck reaction in aqueous solution

作者：Shao, Linjun[1];Liu, Jie[1];Ye, Yuhang[1];Zhang, Xian-Man[1];Qi, Chenze[1]

机构：[1]Shaoxing Univ, Inst Appl Chem, Shaoxing 312000, Zhejiang, Peoples R China

年份：2011

卷号：25

期号：9

起止页码：699

外文期刊名：APPLIED ORGANOMETALLIC CHEMISTRY

收录：SCI-EXPANDED(收录号：WOS:000294179200010)、、EI(收录号：20113514270673)、Scopus(收录号：2-s2.0-81155160858)、WOS

基金：This work was generously supported by the Natural Science Foundation of Zhejiang Province, People's Republic of China (no. Y-4080450) and Shaoxing University. We would like to thank Professor Q. X. Guo and Dr H. Z. Yu for their kind help for the theoretical calculations.

语种：英文

外文关键词：heterogeneous palladium catalysis; Mizoroki-Heck cross-coupling; fiber mats; electrospinning; aryl iodides

外文摘要：A novel palladium catalyst immobilized on polyacrylonitrile fiber mats (Pd/PAN) was prepared by electrospinning. The catalytic activity and recyclability of the microwave-assisted Pd/PAN fiber mats were examined for the Mizoroki-Heck cross-coupling of aryl iodides with three different acrylates in aqueous solution. The morphology of the prepared Pd/PAN fiber mats was characterized by scanning electron microscopy. The large size of the PAN fiber mat-supported palladium catalyst enables much easier separation from the reaction mixture by simple filtration. Density functional theory calculation indicates that the chelation energy of palladium chloride (PdCl2) with propionitrile (model of PAN) is considerable smaller than that of PdCl2 with water, suggesting that the stability and reactivity of the Pd/PAN fiber mats catalyst could be improved through the surface derivatization with polar functional groups. Copyright (C) 2011 John Wiley & Sons, Ltd.