文献类型：期刊文献

英文题名：K2S2O8-Mediated Oxysulfonylation of Vinyl Azides with Sodium Sulfinates to Access beta-Keto Sulfones in Water

作者：Luo, Mengqiang[1];Ren, Xiaorong[1];Shen, Runpu[1];Qi, Chenze[1];Zhang, Yaohong[1];Wang, Hai[2]

机构：[1]Shaoxing Univ, Sch Chem & Chem Engn, Zhejiang Key Lab Alternat Technol Fine Chem Proc, Shaoxing 312000, Zhejiang, Peoples R China;[2]Shaoxing Univ, Sch Life Sci, Shaoxing 312000, Zhejiang, Peoples R China

年份：2021

卷号：6

期号：10

起止页码：2471

外文期刊名：CHEMISTRYSELECT

收录：SCI-EXPANDED(收录号：WOS:000627830300001)、、WOS

基金：We gratefully acknowledge the financial support from Zhejiang Provincial Natural Science foundation of China (No. LQ16H090004) and Research Project of Shaoxing University (No. 2017LG1003).

语种：英文

外文关键词：β -keto sulfones; K2S2O8; Sodium sulfinates; Vinyl azides; Water

外文摘要：With water as solvent, K2S2O8 mediated facile and efficient synthesis of beta-keto sulfones through oxysulfonylation of vinyl azides with sodium sulfinates is described. The novel procedure has the advantages of being environmentally benign, mild reaction conditions, short reaction time, easy and simple operation, wide tolerance of functional groups, which establish the practical application of this methodology.