文献类型：期刊文献

英文题名：Copper(ii) bromide-catalyzed intramolecular decarboxylative functionalization to form a C(sp3)-O bond for the synthesis of furo[3,2-c]coumarins

作者：Zhang, W.L.[1]; Yue, S.N.[1]; Shen, Y.M.[2]; Hu, H.Y.[3]; Meng, Q.-H.[1]; Wu, H.[1]; Liu, Y.[1]

机构：[1] Jiangsu Key Laboratory of Green Synthesis for Functional Materials, School of Chemistry and Chemical Engineering, Jiangsu Normal University, Xuzhou, Jiangsu, 221116, China; [2] School of Chemistry and Chemical Engineering, Shaoxing University, Shaoxing, Zhejiang, China; [3] Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials, School of Chemistry and Chemical Engineering, Huaiyin Normal University, Huaian, Jiangsu, 223300, China

年份：2015

卷号：13

期号：12

起止页码：3602

外文期刊名：Organic and Biomolecular Chemistry

收录：EI(收录号：20151200666609)、Scopus(收录号：2-s2.0-84925068445)

语种：英文

外文关键词：Reaction intermediates - Copper compounds - Catalysis

外文摘要：An efficient and eco-friendly copper(ii) bromide-catalyzed intramolecular decarboxylative functionalization to form a C(sp3)-O bond for the synthesis of furo[3,2-c]coumarins has been developed. In this reaction, a copper(ii) bromide-catalyzed intramolecular decarboxylative functionalization of α-carbonyl is successfully realized to generate an α-bromo carbonyl compound as a key intermediate. ? 2015 The Royal Society of Chemistry.