文献类型：期刊文献

英文题名：Crystalline mesoporous gamma-Al2O3 supported palladium: Novel and efficient catalyst for Suzuki-Miyaura reaction under controlled microwave heating

作者：Feng, Gaofeng[1];Liu, Fujian[1];Lin, Chen[1];Li, Weiting[1];Wang, Shengnan[1];Qi, Chenze[1]

机构：[1]Shaoxing Univ, Zhejiang Key Lab Alternat Technol Fine Chem Proc, Shaoxing 312000, Peoples R China

年份：2013

卷号：37

起止页码：27

外文期刊名：CATALYSIS COMMUNICATIONS

收录：SCI-EXPANDED(收录号：WOS:000319645000007)、、WOS

基金：Financial support by the University of Shaoxing is acknowledged with thanks. We also thank Dr. Fujian Liu in Zhejiang University for discussions and help.

语种：英文

外文关键词：Mesoporous material; Heterogeneous catalysis; Suzuki-Miyaura reaction; gamma-Al2O3

外文摘要：Crystalline mesoporous gamma-Al2O3 has been successfully synthesized under high temperature hydrothermal conditions and used as an excellent support for Pd(OAc)(2). The resulting gamma-Al2O3-Pd showed excellent catalytic activity for Suzuki-Miyaura cross-coupling reaction. As low as 0.2 mol% loading of Pd was needed to obtain cross-coupling products in good to excellent yields in aqueous DMF under microwave irradiation. Moreover, the novel catalyst can be easily recovered by filtration and reused without any diminishing observable activity after five runs. (C) 2013 Elsevier B.V. All rights reserved.