文献类型：期刊文献

英文题名：A facile synthesis strategy of fungi-derived porous carbon-based iron oxides composite for asymmetric supercapacitors

作者：Zhao, Shanhai[1];Zheng, Ke[2];Zhang, Zhifang[3];Wang, Haibing[1];Ren, Junfeng[1];Li, Huiyu[1];Jiang, Feng[1];Liu, Yongsheng[1];Cao, Haijing[1];Fang, Zebo[4];Zhu, Yanyan[1]

机构：[1]Shanghai Univ Elect Power, Coll Math & Phys, Shanghai 200090, Peoples R China;[2]Dongguan Univ Technol, Sch Mat Sci & Engn, Dongguan 523808, Peoples R China;[3]Fudan Univ, Dept Phys, Shanghai 200433, Peoples R China;[4]Shaoxing Univ, Dept Phys, Shaoxing 312000, Peoples R China

年份：2022

卷号：48

期号：7

起止页码：9197

外文期刊名：CERAMICS INTERNATIONAL

收录：SCI-EXPANDED(收录号：WOS:000770442000002)、、EI(收录号：20215111370605)、Scopus(收录号：2-s2.0-85121448100)、WOS

基金：Acknowledgements This work was supported by the National Natural Science Foundation of China (Nos. 51971128, 52171185 and 51872186) ; Program of Shanghai Academic/Technology Research Leader (No.20XD1401800) ; Science and Technology Commission of Shanghai Municipality (No. 19020501000) .

语种：英文

外文关键词：Calcination; Electrical properties; Nanocomposites; Supercapacitors; Transition metal oxides; Fungi-derived carbon

外文摘要：Transition metal oxides (TMOs) have been considered as potential anode materials for asymmetric supercapacitors due to their high theoretical capacities. However, undesirable electric conductivity limits the further application in future energy storage. Here, a honeycomb-like architecture of FeOx embedded in the fungi-derived porous carbon-based material (FeOx/C) for asymmetric supercapacitor was reported. The facile synthesis strategy of fungi-derived porous carbon-based iron oxides was using the carbon derived from fungi and the process of carbothermal reduction to form the iron oxide compound. This carbon-encapsulated iron oxide compound provides highly specific surface area (The specific surface area of Fe-O-C-650 was largest (up to 219.0905 m2/g) compared with samples of Fe-O-C-550(144.0304 m2/g), Fe-O-C-750(201.7352 m2/g), Fe-O-C850(163.2206 m2/g).), an abundance of redox sites, sufficient efficient channels for fast transportation of ions, excellent electrical conductivity, and stable skeleton. Under the three-electrode test system, the FeOx/C electrode delivers excellent specific capacitance of 565F/g at 1 mV/s and impressive cycling performance with capacitance retention of 100% after 3000 cycles. And the NiO electrode delivers a high specific capacitance of 425 F/g at a high current density of 5 mV/s. In addition, the FeOx/C//NiO asymmetric supercapacitor was assembled which exhibits remarkable specific capacitance of 111F/g at 10 mV/s and gravimetric energy density of 36 Wh/kg as well as gravimetric power density of 800W/kg with capacitance retention of 100% after 20,000 cycles, approaching those of ions capacitors.