文献类型：期刊文献

中文题名：芳基磺酰和亚磺酸类化合物参与的偶联反应研究进展

英文题名：Research Progress on Cross-Coupling with Aryl Sulfonyl and Sulfinate Compounds

作者：张诗浓[1,2];杨胜虎[1];黄乐浩[1];赵保丽[1];程凯[1];齐陈泽[1]

机构：[1]绍兴文理学院浙江省精细化学品传统工艺替代技术研究重点实验室,绍兴312000;[2]绍兴市质量技术监督检测院,绍兴312000

年份：2015

卷号：35

期号：11

起止页码：2259

中文期刊名：有机化学

外文期刊名：Chinese Journal of Organic Chemistry

收录：SCI-EXPANDED(收录号：WOS:000367639900002)、CSTPCD、、北大核心2014、CSCD2015_2016、Scopus(收录号：2-s2.0-84951267414)、WOS、北大核心、CSCD

基金：Project supported by the National Natural Science Foundation of China (No. 21402123), the Zhejiang Provincial Natural Science Foundation (Nos. LQ14B020001, LQ13B020001), the Undergraduate Science Technology Innovation of Zhejiang Province (No. 2014R426012), the Education Department of Zhejiang Province (No. Y201328443) and the Foundation of Science and Technology Bureau of Shaoxing (No. 2013B70018).

语种：中文

中文关键词：芳基磺酰类化合物;芳基亚磺酸类化合物;偶联反应;芳基化;芳磺酰化;芳硫化

外文关键词：aryl sulfonyl compounds; arylsulfinate compounds; cross-coupling; arylation; arylsulfonylation; aryl sulfidation;

中文摘要：芳基磺酰和亚磺酸类化合物参与的偶联反应是近年来发展起来的一类高效的合成方法.芳基磺酰氯、芳基亚磺酸（钠）,芳基磺酰肼等可以作为脱硫性芳基化、芳磺酰化和还原性芳硫化的试剂合成各种联芳烃、芳基砜类化合物和芳基硫醚化合物.综述了近几年芳基磺酰类化合物参与的偶联反应研究发展,结合本课题组的工作,探讨了该类化合物在C—C键、C—SO2键和C—S键的构筑方面的新应用和新进展.

外文摘要：Cross-coupling reactions of aryl sulfonyl and sulfinate compounds have been well developed as an efficient synthetic method in recent years. Aryl sulfonyl chlorides, arylsulfinates and arylsulfonyl hydrazides have been used as desulfitative arylation, arylsulfonylation and reductive aryl sulfidation reagents in the synthesis of biaryls, aryl sulfones and aryl sulfides. The research progress on cross-coupling with aryl sulfonyl and sulfinate compounds combined with our work is reviewed, focusing on applications and progress in new synthetic method to construct carbon-carbon, carbon-sulfonyl and carbon-sulfur bond.