文献类型：期刊文献

英文题名：Palladium-catalyzed desulfitative cross-coupling of arylsulfinates with arylboronic acids

作者：Cheng, Kai[1];Yu, Hai-Zhu[2];Zhao, Baoli[1];Hu, Sai[3];Zhang, Xian-Man[1];Qi, Chenze[1]

机构：[1]Shaoxing Univ, Zhejiang Key Lab Alternat Technol Fine Chem Proc, Shaoxing 312000, Peoples R China;[2]Univ Sci & Technol Beijing, Dept Polymer Sci & Engn, Beijing 100083, Peoples R China;[3]Ningbo Univ, Coll Mat Sci & Chem Engn, Ningbo 310014, Zhejiang, Peoples R China

年份：2014

卷号：4

期号：101

起止页码：57923

外文期刊名：RSC ADVANCES

收录：SCI-EXPANDED(收录号：WOS:000345651600075)、、EI(收录号：20144600209654)、Scopus(收录号：2-s2.0-84909969457)、WOS

基金：The authors acknowledge the financial support from the National Natural Science Foundation of China (no. 21402123 and 21202102), the Zhejiang Provincial Natural Science Foundation of China (no. LQ14B020001), and the Science Technology Project of Shaoxing City (no. 2013014017).

语种：英文

外文关键词：Copper compounds - Palladium

外文摘要：Palladium (Pd)-catalyzed desulfitative cross-coupling reactions of sodium arylsulfinates with a wide variety of arylboronic acids were achieved in good to excellent yields under simple aerobic conditions. These catalytic reactions could be accelerated by addition of a catalytic amount of Cu(II) salts as co-catalyst. Moreover, these reactions were tolerant to all of the tested functional groups, making them attractive alternatives to the traditional cross-coupling reactions.