文献类型：期刊文献

英文题名：Palladium-Catalyzed Hiyama-Type Cross-Coupling Reactions of Arenesulfinates with Organosilanes

作者：Cheng, Kai[1,3];Hu, Sai[2];Zhao, Baoli[1];Zhang, Xian-Man[1];Qi, Chenze[1]

机构：[1]Shaoxing Univ, Zhejiang Key Lab Alternat Technol Fine Chem Proc, Shaoxing 312000, Peoples R China;[2]Ningbo Univ, Coll Mat Sci & Chem Engn, Ningbo 310014, Zhejiang, Peoples R China;[3]Zhejiang Huangma Chem Ind Grp Co Ltd, Shangyu 312363, Zhejiang, Peoples R China

年份：2013

卷号：78

期号：10

起止页码：5022

外文期刊名：JOURNAL OF ORGANIC CHEMISTRY

收录：SCI-EXPANDED(收录号：WOS:000319721200038)、、EI(收录号：20132216373285)、Scopus(收录号：2-s2.0-84878075120)、WOS、CCR-EXPANDED(收录号：WOS:000319721200038)

基金：This study was financially supported by the National Science Foundation of China (Grant No. 21172149) and the Science Technology Department of Zhejiang Province (Grant No. 2012R10014-15).

语种：英文

外文关键词：Carbon - Catalysis - Fluorine compounds - Palladium

外文摘要：Palladium-catalyzed Hiyama-type cross-coupling reactions of various arenesulfinates with organosilanes were achieved in good to excellent yields under aerobic conditions at 70 degrees C. Fluoride is essential, and tetrabutylammonium fluoride (TBAF) was shown to be the most efficient additive for these cross-coupling reactions. These cross-coupling reactions of the arenesulfinates provide high yields and show wide functional group tolerance, making them attractive alternative transformations to traditional cross-coupling approaches for carbon-carbon bond construction.