文献类型：期刊文献

英文题名：Pd-catalyzed ligand-free desulfitative Heck reaction with arenesulfinic acid salts under air

作者：Hu, Sai[1];Xia, Ping[3];Cheng, Kai[2];Qi, Chenze[2]

机构：[1]Ningbo Univ, Coll Mat Sci & Chem Engn, Ningbo 310014, Zhejiang, Peoples R China;[2]Univ Shaoxing, Zhejiang Key Lab Alternat Technol Fine Chem Proc, Shaoxing 312000, Zhejiang, Peoples R China;[3]Henan Univ Technol, Coll Chem & Chem Engn, Zhengzhou 450001, Peoples R China

年份：2013

卷号：27

期号：3

起止页码：188

外文期刊名：APPLIED ORGANOMETALLIC CHEMISTRY

收录：SCI-EXPANDED(收录号：WOS:000315484200011)、、EI(收录号：20131016086161)、Scopus(收录号：2-s2.0-84874473226)、WOS、CCR-EXPANDED(收录号：WOS:000315484200011)

基金：This study was supported by the National Science Foundation of China (Grant No. 21172149) and the Science Technology Department of Zhejiang Province (Grant No. 2012R10014-15).

语种：英文

外文关键词：Pd-catalyzed; desulfitative coupling; Heck coupling

外文摘要：Palladium-catalyzed cross-coupling reactions of various aryl sulfinic acid salts with a wide variety of vinyl substrates have been achieved in good to excellent yields under simple aerobic conditions at 70 degrees C with the assistance of Cu(II) salts. The reaction can be accelerated by the combination of DMSO with THF. The reported MatsudaHeck type coupling reactions are tolerant to the common functional groups, making these transformations as attractive alternatives to the traditional cross-coupling approaches. Copyright (c) 2013 John Wiley & Sons, Ltd.