文献类型：期刊文献

英文题名：Investigation of the Effect of Alkyl Chain Length on Molecular Interactions Between Methyl Benzoate with Alcohols: A Study of Physicochemical Properties

作者：Chen, Tingting[1];Feng, Xiao[1];Yin, Yuqiao[1];Xu, Yingjie[1]

机构：[1]Shaoxing Univ, Dept Chem, Shaoxing 312000, Peoples R China

年份：2020

卷号：49

期号：11

起止页码：1402

外文期刊名：JOURNAL OF SOLUTION CHEMISTRY

收录：SCI-EXPANDED(收录号：WOS:000575763400001)、、EI(收录号：20242616307069)、Scopus(收录号：2-s2.0-85092127678)、WOS

基金：This work was supported by the National Science Foundation of China (No. 21978172), National Natural Science Foundation of Zhejiang Province (No. Y18B060014), National Undergraduate Training Program for Innovation and Entrepreneurship (No. 201810349013), Undergraduate Scientific and Technological Innovation Project of Shaoxing University, the Key Teacher Training Research of Shaoxing University (No. 2016227).

语种：英文

外文关键词：Physicochemical property; Methyl benzoate; Microstructure; Hydrogen bond interaction

外文摘要：Densities, speeds of sound, and viscosities of binary mixtures of methyl benzoate (MB) with ethanol, 1-propanol, and 1-butanol were measured at temperature ranging fromT = 293.2 to 313.2 K and refractive indices were determined atT = 303.2 K. Excess molar volumes,V-E, isentropic compressibility deviations increment kappa(s)and viscosity deviations, Delta eta, were obtained and fitted with the Redlich-Kister equation with satisfactory results. Based on the measured and derived physicochemical properties, the influence of the alkyl chain length of the alcohol on the molecular interactions of the studied mixtures was explored. The results show that both hydrogen bond interaction between carbonyl group of MB and hydroxyl group of alcohol and the packing efficiency, such as accommodation of alcohol in the interstice of MB, play an important role in the microstructure of the mixtures, which leads to the disruption of alcohol with the addition of MB. Moreover, by comparingV(E), increment kappa(s)and Delta eta values of MB (1) + alcohol (2) systems atT = 303.2 K, it is found that the strength of hydrogen bond interaction and the packing efficiency significantly weakens with increasing alkyl chain length of alcohol in going from ethanol to 1-butanol, resulting in theV(E)values of the studied systems gradually changing from a negative deviation to an S shape, the increment kappa(s)and Delta eta values have negative deviations, and the increment n(D)values have positive deviations. The obtained results will provide thermodynamic guidance for the industrial purification of methyl benzoate.