文献类型：期刊文献

英文题名：ortho-Alkynyl Benzyl Alcohols as C6 Synthons in Regioselective Construction of Polysubstituted Naphthalenes

作者：Wei, Xuemei[1,2]; Cai, Tao[1,2]; Zhang, Zhebing[1]; Luo, Yanjuan[1,2]; Shang, Tianbo[1,2]; Shen, Hualiang[1,2]; Xu, Huiting[1,2]; Yu, Lemao[1]; Luo, Xiang[1]; Yu, Guoqi[2]; Shen, Runpu[1,2]

机构：[1] College of Chemistry and Chemical Engineering, Shaoxing University, Shaoxing, 312000, China; [2] Zhejiang Engineering Research Center of Fat-Soluble Vitamin, Shaoxing University, Shaoxing, 312000, China

年份：2024

外文期刊名：Journal of Organic Chemistry

收录：EI(收录号：20242016104355)、Scopus(收录号：2-s2.0-85193067628)

语种：英文

外文关键词：Additives - Transition metals

外文摘要：A straightforward methodology for the assembly of polysubstituted naphthalenes from ortho-alkynyl benzyl alcohols, enabled by using catalytic amounts of Tf2O, has been developed. This transformation not only features transition-metal free and without using other bases and additives but also provides a new synthetic application for ortho-alkynyl benzyl alcohols, i.e., as C6 synthons for the construction of PAHs. ? 2024 American Chemical Society