文献类型：期刊文献

英文题名：Copper(II) bromide-catalyzed intramolecular decarboxylative functionalization to form a C(sp(3))-O bond for the synthesis of furo[3,2-c]-coumarins

作者：Zhang, W. L.[1,2];Yue, S. N.[1,2];Shen, Y. M.[3];Hu, H. Y.[4];Meng, Q-H.[1,2];Wu, H.[1,2];Liu, Y.[1,2]

机构：[1]Jiangsu Normal Univ, Jiangsu Key Lab Green Synth Funct Mat, Xuzhou 221116, Jiangsu, Peoples R China;[2]Jiangsu Normal Univ, Sch Chem & Chem Engn, Xuzhou 221116, Jiangsu, Peoples R China;[3]Shaoxing Univ, Sch Chem & Chem Engn, Shaoxing, Zhejiang, Peoples R China;[4]Huaiyin Normal Univ, Jiangsu Key Lab Chem Low Dimens Mat, Sch Chem & Chem Engn, Huaian 223300, Jiangsu, Peoples R China

年份：2015

卷号：13

期号：12

起止页码：3602

外文期刊名：ORGANIC & BIOMOLECULAR CHEMISTRY

收录：SCI-EXPANDED(收录号：WOS:000351352100012)、、WOS、CCR-EXPANDED(收录号：WOS:000351352100012)

基金：The authors gratefully acknowledge the National Natural Science Foundation of China (NSFC 21172188, 21202101, 21202058), the Key Project of Natural Science Research of Universities in Jiangsu Province (14KJA430003), and the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) for financial support of this work.

语种：英文

外文关键词：Carbonyl compounds - Catalysis - Reaction intermediates

外文摘要：An efficient and eco-friendly copper(II) bromide-catalyzed intramolecular decarboxylative functionalization to form a C(sp(3))-O bond for the synthesis of furo[3,2-c]coumarins has been developed. In this reaction, a copper(II) bromide-catalyzed intramolecular decarboxylative functionalization of a-carbonyl is successfully realized to generate an a-bromo carbonyl compound as a key intermediate.