文献类型：期刊文献

英文题名：Comparison of the alkalinity of hydroxypyridine anion-based protic ionic liquids and their catalytic performance for Knoevenagel reaction: The effect of the type of cation and the position of nitrogen atom of anion

作者：Xie, Bin[1];Xu, Yingjie[1];Tang, Xiaochen[1];Shu, Hegang[1];Chen, Tingting[1];Zhu, Xiao[2]

机构：[1]Shaoxing Univ, Dept Chem, Shaoxing 312000, Zhejiang, Peoples R China;[2]Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 273165, Peoples R China

年份：2018

卷号：268

起止页码：610

外文期刊名：JOURNAL OF MOLECULAR LIQUIDS

收录：SCI-EXPANDED(收录号：WOS:000447817400068)、、EI(收录号：20183105618664)、Scopus(收录号：2-s2.0-85050510279)、WOS

基金：We are grateful to the Natural Science Foundation of Zhejiang Province (Y18B060014), National Natural Science Foundation of China (21406140), and National Under-graduate Training Program for Innovation and Entrepreneurship (No. 201810349013) for financial support.

语种：英文

外文关键词：Ionic liquid; Alkalinity; Knoevenagel reaction

外文摘要：The design of acidity and alkalinity is an important characteristic of ionic liquids, and it also affects their application. For this reason, the alkalinity of six hydroxypyridine anion-based protic ionic liquids (PILs) was determined by potentiometric titration, and the effect of the type of cation and the position of nitrogen atom of anion on the alkalinity was discussed. Furthermore, six hydroxypyridine anion-based PILs were used as catalysts for Knoevenagel reaction, and the relationship between the catalytic performance and the alkalinity was investigated. The results indicate that the type of cation has little effect on the alkalinity of the studied PILs, while the position of nitrogen atom of anion has a significant influence on the alkalinity, and the order of the alkalinity is as follows: [2 Op](-) > [4 Op](-) > [3 Op](-), resulting from the positive cooperative interaction between electronegative nitrogen and oxygen atoms, which is confirmed by OFT calculation. Consequently, the PILs with [2 Op](-) anion showing stronger alkalinity exhibits better catalytic performance for Knoevenagel reaction. (C) 2018 Elsevier B.V. All rights reserved.