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Aqua(dicyanamido){mu-6,6 '-dimethoxy-2,2 '-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II)sodium  ( SCI-EXPANDED收录)   被引量:11

文献类型:期刊文献

英文题名:Aqua(dicyanamido){mu-6,6 '-dimethoxy-2,2 '-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II)sodium

作者:Wang, Wei[2];Shen, Yong-Miao[1]

机构:[1]Shaoxing Univ, Dept Chem, Shaoxing 312000, Peoples R China;[2]Yancheng Inst Technol, Sch Chem & Biol Engn, Yancheng 224003, Peoples R China

年份:2009

卷号:65

起止页码:M557

外文期刊名:ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS

收录:SCI-EXPANDED(收录号:WOS:000265702000068)、、Scopus(收录号:2-s2.0-66749101366)、WOS

基金:This work was supported by the Zhejiang Provincial Natural Science Foundation (grant No. Y4080395).

语种:英文

外文摘要:The molecule of the title compound, [NaNi(C18H18N2O4)(C2N3)(H2O)], is approximately planar, with a maximum deviation from the molecular plane of 0.770 (5) angstrom. The coordination environment of the Ni2+ ion is distorted square-planar and it is N2O2 coordinated by the 6,6'-dimethoxy-2,2'-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolate Schiff base ligand. The Na+ atom is chelated by the four O atoms of the Schiff base ligand, a water ligand and a dicyanamide anion. The structure displays intermolecular O-H center dot center dot center dot N hydrogen bonding.

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