文献类型：期刊文献

英文题名：ortho-Alkynyl Benzyl Alcohols as C6 Synthons in Regioselective Construction of Polysubstituted Naphthalenes

作者：Wei, Xuemei[1,2];Cai, Tao[1,2];Zhang, Zhebing[1];Luo, Yanjuan[1,2];Shang, Tianbo[1,2];Shen, Hualiang[1,2];Xu, Huiting[1,2];Yu, Lemao[1];Luo, Xiang[1];Yu, Guoqi[2];Shen, Runpu[1,2]

机构：[1]Shaoxing Univ, Coll Chem & Chem Engn, Shaoxing 312000, Peoples R China;[2]Shaoxing Univ, Zhejiang Engn Res Ctr Fat Soluble Vitamin, Shaoxing 312000, Peoples R China

年份：2024

外文期刊名：JOURNAL OF ORGANIC CHEMISTRY

收录：SCI-EXPANDED(收录号：WOS:001225240500001)、、WOS

基金：We gratefully thank the financial support from the Natural Science Foundation of China (Grant No. 22278270), the Shaoxing Basic Public Welfare Project (No. 2023A11003), and the Research Project of Shaoxing University (No. 2023LG003).

语种：英文

外文摘要：A straightforward methodology for the assembly of polysubstituted naphthalenes from ortho-alkynyl benzyl alcohols, enabled by using catalytic amounts of Tf2O, has been developed. This transformation not only features transition-metal free and without using other bases and additives but also provides a new synthetic application for ortho-alkynyl benzyl alcohols, i.e., as C6 synthons for the construction of PAHs.