文献类型：期刊文献

英文题名：Enhanced catalytic performance in dehydration of sorbitol to isosorbide over a superhydrophobic mesoporous acid catalyst

作者：Zhang, Jian[1];Wang, Liang[1];Liu, Fujian[1,2];Meng, Xiangju[1];Mao, Jianxin[1];Xiao, Feng-Shou[1]

机构：[1]Zhejiang Univ, Dept Chem, Key Lab Appl Chem Zhejiang Prov, Hangzhou 310028, Zhejiang, Peoples R China;[2]Shaoxing Univ, Key Lab Alternat Technol Fine Chem Proc Zhejiang, Shaoxing 312000, Peoples R China

年份：2015

卷号：242

期号：PB

起止页码：249

外文期刊名：CATALYSIS TODAY

收录：SCI-EXPANDED(收录号：WOS:000345993200003)、、EI(收录号：20145200361215)、Scopus(收录号：2-s2.0-84919333536)、WOS

基金：This work is supported by National Natural Science Foundation of China (21273197, U1162201, and 21333009) and National High-Tech Research and Development program of China (2013AA065301).

语种：英文

外文关键词：Superhydrophobicity; Porous polymer; Solid acid; Biomass; Sorbitol dehydration

外文摘要：A superhydrophobic mesoporous polymer-based acid catalyst (P-SO3H) was synthesized from solvothermal co-polymerization. The N-2 sorption isotherms indicate the rich porosity of P-SO3H, confirmed by the TEM image. The IR spectra indicate the presence of sulfonic acid groups. Interestingly, P-SO3H gives contact angle of water droplet on the sample surface at 154 degrees, suggesting its superhydrophobicity. More importantly, P-SO3H is highly efficient catalyst for dehydration of sorbitol to isosorbide, giving sorbitol conversion higher than 99.0% and isosorbide yield at 87.9%. In addition, P-SO3H exhibits excellent recyclability. After recycles for 5 times, the isosorbide yield is still 77.7%. In contrast, conventional acid catalyst of Amberlyst-15 shows the yield at only 15.4% after recycles for 3 times. The unique catalytic properties are reasonably related to the superhydrophobicity and porosity of P-SO3H. The sample large porosity offers a high degree of the exposed acidic sites to the reactants, and the sample superhydrophobicity would keep the water formed in the dehydration away from the catalyst, promoting the reaction equilibrium. As a result, the catalytic performance in dehydration of sorbitol to isosorbide over the superhydrophobic P-SO3H catalyst is significantly enhanced, compared with conventional acid catalyst of Amberlyst-15. (C) 2014 Published by Elsevier B.V.