文献类型：期刊文献

英文题名：Metal-organic framework nanocrystal-derived hollow porous materials: Synthetic strategies and emerging applications

作者：Liu, Xiaolu[1,2];Verma, Gaurav[3];Chen, Zhongshan[1];Hu, Baowei[2];Huang, Qifei[4];Yang, Hui[1];Ma, Shengqian[3];Wang, Xiangke[1,2]

机构：[1]North China Elect Power Univ, Coll Environm Sci & Engn, Beijing 102206, Peoples R China;[2]Shaoxing Univ, Sch Life Sci, Huancheng West Rd 508, Shaoxing 312000, Peoples R China;[3]Univ North Texas, Dept Chem, 1508 W Mulberry St, Denton, TX 76201 USA;[4]Chinese Res Inst Environm Sci, State Key Lab Environm Criteria & Risk Assessment, Beijing 100012, Peoples R China

年份：2022

卷号：3

期号：5

外文期刊名：INNOVATION

收录：EI(收录号：20230813629831)、ESCI(收录号：WOS:000836816300003)、Scopus(收录号：2-s2.0-85134734144)、WOS

基金：Financial support from the National Key Research and Development Program of China (2018YFC1900105), NSFC (22006036; U2167218), and Beijing Outstanding Young Scientist Program is greatly appreciated.

语种：英文

外文摘要：Metal-organic frameworks (MOFs) have garnered multidisciplinary attention due to their structural tailorability, controlled pore size, and physicochemical functions, and their inherent properties can be exploited by applying them as precursors and/or templates for fabricating derived hollow porous nanomaterials. The fascinating, functional properties and applications of MOF derived hollow porous materials primarily lie in their chemical composition, hollow character. and unique porous structure. Herein, a comprehensive over view of the synthetic strategies and emerging applications of hollow porous materials derived from MOF-based templates and/or precursors is given. Based on the role of MOFs in the preparation of hollow porous materials, the synthetic strategies are described in detail, including (1) MOFs as removable templates, (2) MOF nanocrystals as both self-sacrificing templates and precursors, (3) MOF@secondary-component core-shell composites as precursors, and (4) hollow MOF nanocrystals and their composites as precursors. Subsequently, the applications of these hollow porous materials for chemical catalysis, electrocatalysis, energy storage and conversion, and environmental management are presented. Finally, a perspective on the research challenges and future opportunities and prospects for MOF-derived hollow materials is provided.