文献类型：期刊文献

英文题名：Acid-promoted denitrogenative Pd-catalyzed addition of arylhydrazines with nitriles at room temperature

作者：Cheng, Kai[1];Wang, Guofang[1];Meng, Mengting[1];Qi, Chenze[1]

机构：[1]Shaoxing Univ, Zhejiang Key Lab Alternat Technol Fine Chem Proc, Shaoxing 312000, Peoples R China

年份：2017

卷号：4

期号：3

起止页码：398

外文期刊名：ORGANIC CHEMISTRY FRONTIERS

收录：SCI-EXPANDED(收录号：WOS:000395904900012)、、EI(收录号：20184806136852)、Scopus(收录号：2-s2.0-85014267143)、WOS、CCR-EXPANDED(收录号：WOS:000395904900012)

基金：This project is supported by the Zhejiang Provincial Natural Science Foundation of China (No. LQ14B020001), the National Natural Science Foundation of China (No. 21402123 and No. 21172149), and the Science Technology Project of Shaoxing City (No. 2013014017).

语种：英文

外文关键词：Ketones

外文摘要：The Pd(TFA)(2)-catalyzed denitrogenative addition proceeded with selective C-N bond cleavage of arylhydrazines with nitriles in the presence of DABCO and HFBA under air at room temperature. Aryl ketones could be easily synthesized via the hydrolysis of the ketimine moiety generated in situ without the need for additional water.