文献类型：期刊文献

英文题名：Denitrogenative Pd/Cu-catalyzed Suzuki-type Cross-coupling of Aryltrifluoroborates with Arylhydrazine Hydrochlorides in Water under Room Temperature

作者：Wang, Guofang[1];Meng, Mengting[1];Deng, Liping[1];Cheng, Kai[1,2];Qi, Chenze[1]

机构：[1]Shaoxing Univ, Zhejiang Key Lab Alternat Technol Fine Chem Proc, Shaoxing 312000, Peoples R China;[2]Heidelberg Univ, Organ Chem Inst, Neuenheimer Feld 270, D-69120 Heidelberg, Germany

年份：2018

卷号：32

期号：3

外文期刊名：APPLIED ORGANOMETALLIC CHEMISTRY

收录：SCI-EXPANDED(收录号：WOS:000426058000091)、、EI(收录号：20175204578719)、Scopus(收录号：2-s2.0-85038818355)、WOS、CCR-EXPANDED(收录号：WOS:000426058000091)

基金：This work was Supported by the National Natural Science Foundation of China (No. 21402123 and No. 21172149), the Science Technology Project of Shaoxing City (No. 2017B70053) and the Zhejiang Provincial Natural Science Foundation of China (No. LY18B020006 and No. LQ14B020001).

语种：英文

外文关键词：arylhydrazide hydrochlorides; aryltrifluoroborates; Suzuki-type cross-coupling; water; water-soluble Pd-catalyzed

外文摘要：A water-soluble palladium-catalyzed Suzuki-type cross-coupling of aryltrifluoroborates with arylhydrazide hydrochlorides was efficiently developed under mild and environmentally benign conditions, in water without any ligand. The newly developed Pd/Cu co-catalyzed denitrogenative reaction gave a range of structurally diverse substituted biaryls with good to excellent yields, in which the byproduct was nitrogen.