文献类型：期刊文献

英文题名：Synergistic Visible Light and Pd-Catalyzed C-H Alkylation of 1-Naphthylamines with ?-Diazoesters

作者：Zhao, Baoli[1,2];Li, Haifeng[2];Jiang, Fengxuan[2];Wan, Jie-Ping[1];Cheng, Kai[2];Liu, Yunyun[1]

机构：[1]Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Peoples R China;[2]Shaoxing Univ, Zhejiang Key Lab Alternat Technol Fine Chem Proc, Shaoxing 312000, Peoples R China

年份：0

外文期刊名：JOURNAL OF ORGANIC CHEMISTRY

收录：SCI-EXPANDED(收录号：WOS:000951943300001)、、EI(收录号：20225213294759)、Scopus(收录号：2-s2.0-85144467181)、WOS、CCR-EXPANDED(收录号：WOS:000951943300001)

基金：This work is financially supported by the National Natural Science Foundation of China (21402123) and the Zhejiang Provincial Natural Science Foundation of China (No. LY18B020006) .

语种：英文

外文摘要：The combination of visible light irradiation and Pd catalysis has been practically employed for the C-H alkylation reactions of naphthylamines and alpha-diazo esters, leading to the synthesis of alpha-naphthyl functionalized acetates via C-C bond construction under mild reaction conditions and under solvent-free conditions. The light irradiation has been proven to play a pivotal role in the reactions, probably by promoting the generation of active carbene species from alpha-diazo esters.